Beilstein J. Org. Chem.2016,12, 1314–1321, doi:10.3762/bjoc.12.124
: artificial Diels-Alderase; biohybrid catalysis; copperenyzme; membrane protein; Introduction
So-called artificial metalloenzymes have attracted attention over the last decade [1][2][3][4][5][6][7][8][9]. Incorporation of an organometallic cofactor into proteins offers new possibilities to expand the
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Graphical Abstract
Scheme 1:
Syntheses to Cu(I) complex bearing a NHC ligand.